Safety data sheet for Zinc chloride

CAS 7646-85-7

This is the free preview of a draft SDS for Zinc chloride — Sections 1, 2 and 9, generated from the sources named below. The full 16-section draft, with your own company in Section 1, is $5 per document.

Typically documented by: Soldering flux, wood preservative.

Draft safety data sheet — preview

Sections 1, 2, 9 of 16

CAS number
7646-85-7
Molecular formula
Cl2Zn
Molecular weight
136.3 g/mol
Signal word
Danger

Hazard classification

  • GHS05 — Corrosive
  • GHS07 — Health hazard — irritant
  • GHS09 — Hazardous to the environment
  • H302: Harmful if swallowed.
  • H314: Causes severe skin burns and eye damage.
  • H400: Very toxic to aquatic life.
  • H410: Very toxic to aquatic life with long lasting effects.

Section 1 — Identification

1.1 Product identifier

Product identifier: Zinc Chloride

Chemical name (IUPAC): dichlorozinc

CAS number: 7646-85-7

PubChem CID reference: 5727

Synonyms: Dichlorozinc; Zinkchloride; Zintrace; Zinc chloride fume; Zinc chloride (ZnCl2); Zine dichloride; Zinc (chlorure de); Zinco (cloruro di); EPA Pesticide Chemical Code 087801; AI3-04470

Section 2 — Hazards Identification

2.1 Classification of the substance or mixture

Classification basis: OSHA 29 CFR 1910.1200 Appendix A, aligned to the GHS Rev. 7 hazard classes this sheet resolves: Acute Tox. 4 (Oral), Skin Corr. 1A.

Classification: Acute Toxicity, Category 4 — Oral (Acute Tox. 4 (Oral)) [H302]

Classification: Skin Corrosion, Category 1A (Skin Corr. 1A) [H314]

2.2 Label elements

Signal word: Danger

GHS pictograms: GHS05 (Corrosion), GHS07 (Exclamation), GHS09 (Environmental Hazard)

Hazard statement: H302: Harmful if swallowed.

Hazard statement: H314: Causes severe skin burns and eye damage.

Hazard statement: H400: Very toxic to aquatic life.

Hazard statement: H410: Very toxic to aquatic life with long lasting effects.

Precautionary statement: P260: Do not breathe dust/fume/gas/mist/vapors/spray.

Precautionary statement: P264+P265: Wash hands thoroughly after handling. Do not touch eyes.

Precautionary statement: P280: Wear protective gloves, protective clothing, eye protection, face protection, and hearing protection.

Precautionary statement: P305+P354+P338: IF IN EYES: Immediately rinse with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.

Precautionary statement: P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

Precautionary statement: P302+P361+P354: IF ON SKIN: Take off immediately all contaminated clothing. Immediately rinse with water for several minutes.

Section 9 — Physical and Chemical Properties

9.1 Information on basic physical and chemical properties

Physical form: Solid

Appearance: White, very deliquesce granules, or fused pieces or rods

Odor: Odorless

Boiling point: 732.2°C (1350°F) at 1013 hPa

Melting point: 290°C (554°F)

Density: 2.907 at 25 °C

Vapor pressure: 0 hPa at 305°C

Water solubility: Solubility in water, g/100ml at 25 °C: 432 (very good)

pH: Aqueous solutions of zinc chloride are acidic (pH = 1.0 for 6 M)

Not found in the public records searched: flash point, Log Pow (log Kow), vapor density, lower explosive limit, upper explosive limit, auto-ignition temperature and viscosity. Enter these from your supplier's safety data sheet or your own test report before the draft is issued.

Occupational exposure limits for Zinc chloride

The airborne limits on public record in the United States. These are transcribed from the tables named in each row, not derived. The full draft puts them in Section 8 with the control and PPE guidance.

OSHA PEL — TWA (8 h)

1 mg/m³

OSHA Annotated PEL Table Z-1

NIOSH REL — TWA (up to 10 h)

1 mg/m³

OSHA Annotated PEL Table Z-1 (NIOSH REL column)

NIOSH REL — STEL (15 min)

2 mg/m³

OSHA Annotated PEL Table Z-1 (NIOSH REL column)

Where each value came from

Odor — Hazardous Substances Data Bank (HSDB)
O'Neil, M.J. (ed.). The Merck Index - An Encyclopedia of Chemicals, Drugs, and Biologicals. 13th Edition, Whitehouse Station, NJ: Merck and Co., Inc., 2001, p. 1810
View the record
Boiling point — Hazardous Substances Data Bank (HSDB)
Same reference as odor above.
View the record
Melting point — Hazardous Substances Data Bank (HSDB)
Same reference as odor above.
View the record
Density — Hazardous Substances Data Bank (HSDB)
Same reference as odor above.
View the record
Water solubility — Hazardous Substances Data Bank (HSDB)
Same reference as odor above.
View the record
pH — Hazardous Substances Data Bank (HSDB)
Kirk-Othmer Encyclopedia of Chemical Technology. 4th ed. Volumes 1: New York, NY. John Wiley and Sons, 1991-Present, p. V25: 850 (1998)
View the record

A value with no row here was assembled from more than one record, so no single record is credited for it. The draft you buy carries this table as an appendix covering all 16 sections.

Sources

  • ECHA C&L Inventory — harmonised CLP entry
  • Hazardous Substances Data Bank (HSDB)
  • OSHA Annotated PEL Table Z-1
  • OSHA Annotated PEL Table Z-1 (NIOSH REL column)
  • PubChem — GHS classification
  • PubChem — compound record
  • PubChem — names and identifiers
  • PubChem — regulatory information
  • PubChem — toxicity data
  • PubChem — transport information

Sections 1.3 and 1.4 are withheld here because the supplier and emergency contact blocks carry your own company details in the draft you buy. Every draft needs review by a competent person before it is issued.

Measured values for Zinc chloride, and where each one comes from

23 measured values for 7 properties, read from 4 public databases. On 2 properties the records differ. Each reading is shown with its own record. Follow any record to read the value at its source.

Boiling point

4 records agree

Used with vapour pressure to judge how readily the substance reaches the air you breathe.

Melting point

4 records agree

Fixes the physical state at handling temperature, which the label and the transport class depend on.

Vapour pressure

3 records differ

The higher it is, the faster the substance evaporates into the workplace air at room temperature.

0 mmHg (approx)
NIOSH Pocket Guide

Density

4 records differ

Needed to convert between mass and volume on the label, in transport papers and in a spill estimate.

(77 °F): 2.91
NIOSH Pocket Guide

Solubility

5 records, each a different case

Determines spill behaviour, the right extinguishing media and the correct first-aid rinse.

432 g/100 g water at 25 °C; 614 g/100 g water at 100 °C
Hazardous Substances Data Bank (HSDB)
1 gram dissolves in 0.25 mL 2% hydrochloric acid, 1.3 mL alcohol, 2 mL glycerol; freely soluble in acetone
Hazardous Substances Data Bank (HSDB)
100 g/100 cc alcohol at 12.5 °C
Hazardous Substances Data Bank (HSDB)
434.599 lb/100 lb water at 70 °F
Hazardous Substances Data Bank (HSDB)
(70 °F): 435%
NIOSH Pocket Guide

pH

1 record

Drives the skin and eye corrosion classification for solutions, alongside the corrosivity data.

Aqueous solutions of zinc chloride are acidic (pH = 1.0 for 6 M)
Hazardous Substances Data Bank (HSDB)

Odour

2 records, each a different case

Odour is a warning property only. Many substances are hazardous well below the concentration you can smell.

FUME HAS AN ACRID ODOR /ZINC CHLORIDE FUMES/
Hazardous Substances Data Bank (HSDB)

These are the public records read for Zinc chloride, published here unchanged. Where two records disagree, the draft you buy states the value and names the record behind it, so a reviewer can see what was chosen. Every draft needs review by a competent person before it is issued.

Get the full draft SDS for Zinc chloride

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