Safety data sheet for Iron oxide

CAS 1309-37-1

This is the free preview of a draft SDS for Iron oxide — Sections 1, 2 and 9, generated from the sources named below. The full 16-section draft, with your own company in Section 1, is $5 per document.

Typically documented by: Pigment, cosmetics, polishing compound.

Draft safety data sheet — preview

Sections 1, 2, 9 of 16

CAS number
1309-37-1
Molecular formula
Fe2O3
Molecular weight
159.69 g/mol
Signal word
Warning

Hazard classification

  • GHS07 — Health hazard — irritant
  • GHS09 — Hazardous to the environment
  • H319: Causes serious eye irritation.
  • H411: Toxic to aquatic life with long lasting effects.

Section 1 — Identification

1.1 Product identifier

Product identifier: Iron trioxide

Chemical name (IUPAC): oxo(oxoferriooxy)iron

CAS number: 1309-37-1

PubChem CID reference: 518696

Synonyms: Iron trioxide; Iron oxide, red; iron(3+) oxide; iron (III) oxide; Anhydrous Ferric Oxide; Anhydrous Iron (III) Oxide; CHEBI:50819; Ferrum Oxydatum; Iron oxide,; Hematite 8124

Section 2 — Hazards Identification

2.1 Classification of the substance or mixture

Classification basis: OSHA 29 CFR 1910.1200 Appendix A, aligned to the GHS Rev. 7 hazard classes this sheet resolves: Eye Irrit. 2.

Classification: Eye Irritation, Category 2 (Eye Irrit. 2) [H319]

2.2 Label elements

Signal word: Warning

GHS pictograms: GHS07 (Exclamation), GHS09 (Environmental Hazard)

Hazard statement: H319: Causes serious eye irritation.

Hazard statement: H411: Toxic to aquatic life with long lasting effects.

Precautionary statement: P264+P265: Wash hands thoroughly after handling. Do not touch eyes.

Precautionary statement: P280: Wear protective gloves, protective clothing, eye protection, face protection, and hearing protection.

Precautionary statement: P273: Avoid release to the environment.

Precautionary statement: P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

Precautionary statement: P337+P317: If eye irritation persists: Get medical help.

Precautionary statement: P391: Collect spillage.

Section 9 — Physical and Chemical Properties

9.1 Information on basic physical and chemical properties

Physical form: Solid

Appearance: Reddish-brown hexagonal crystals

Melting point: 1539°C (2802°F)

Density: 5.25 g/cm³

Vapor pressure: 0 hPa

Water solubility: none

Not found in the public records searched: odor, boiling point, flash point, Log Pow (log Kow), vapor density, lower explosive limit, upper explosive limit, auto-ignition temperature, viscosity and pH. Enter these from your supplier's safety data sheet or your own test report before the draft is issued.

Occupational exposure limits for Iron oxide

The airborne limits on public record in the United States. These are transcribed from the tables named in each row, not derived. The full draft puts them in Section 8 with the control and PPE guidance.

OSHA PEL — TWA (8 h)

10 mg/m³

NIOSH Pocket Guide to Chemical Hazards, reproducing the OSHA PEL

NIOSH REL — TWA (up to 10 h)

5 mg/m³

OSHA Annotated PEL Table Z-1 (NIOSH REL column)

Where each value came from

Melting point — Hazardous Substances Data Bank (HSDB)
Lide, D.R. CRC Handbook of Chemistry and Physics 88th Edition 2007-2008. CRC Press, Taylor & Francis, Boca Raton, FL 2007, p. 4-69
View the record
Density — Hazardous Substances Data Bank (HSDB)
Same reference as melting point above.
View the record

A value with no row here was assembled from more than one record, so no single record is credited for it. The draft you buy carries this table as an appendix covering all 16 sections.

Sources

  • Hazardous Substances Data Bank (HSDB)
  • NIOSH Pocket Guide to Chemical Hazards, reproducing the OSHA PEL
  • OSHA Annotated PEL Table Z-1 (NIOSH REL column)
  • PubChem — GHS classification
  • PubChem — compound record
  • PubChem — names and identifiers
  • PubChem — regulatory information
  • PubChem — toxicity data
  • PubChem — transport information

Sections 1.3 and 1.4 are withheld here because the supplier and emergency contact blocks carry your own company details in the draft you buy. Every draft needs review by a competent person before it is issued.

Measured values for Iron oxide, and where each one comes from

12 measured values for 4 properties, read from 3 public databases. On 3 properties the records differ. Each reading is shown with its own record. Follow any record to read the value at its source.

Melting point

4 records, 1462 to 1565 °C

Fixes the physical state at handling temperature, which the label and the transport class depend on.

Vapour pressure

3 records differ

The higher it is, the faster the substance evaporates into the workplace air at room temperature.

0 mmHg (approx)
NIOSH Pocket Guide

Density

3 records differ

Needed to convert between mass and volume on the label, in transport papers and in a spill estimate.

Solubility

2 records, each a different case

Determines spill behaviour, the right extinguishing media and the correct first-aid rinse.

Soluble in acids; insoluble in water, alcohol, ether
Hazardous Substances Data Bank (HSDB)

These are the public records read for Iron oxide, published here unchanged. Where two records disagree, the draft you buy states the value and names the record behind it, so a reviewer can see what was chosen. Every draft needs review by a competent person before it is issued.

Get the full draft SDS for Iron oxide

The draft covers all 16 sections under OSHA 29 CFR 1910.1200 and GHS Rev. 7, or the CLP EC 1272/2008 layout for the EU. Each draft arrives as an editable .docx and a PDF with an appendix naming the source of each value, in about 60 seconds. $5 per document, no account.

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