Safety data sheet for Dimethyl sulfoxide

CAS 67-68-5

This is the free preview of a draft SDS for Dimethyl sulfoxide — Sections 1, 2 and 9, generated from the sources named below. The full 16-section draft, with your own company in Section 1, is $5 per document.

Typically documented by: Laboratory solvent, formulation carrier.

Draft safety data sheet — preview

Sections 1, 2, 9 of 16

CAS number
67-68-5
Molecular formula
C2H6OS
Molecular weight
78.14 g/mol
Signal word
None required — not classified

Section 1 — Identification

1.1 Product identifier

Product identifier: Dimethyl Sulfoxide

Chemical name (IUPAC): methylsulfinylmethane

CAS number: 67-68-5

PubChem CID reference: 679

Synonyms: dimethyl sulfoxide; DMSO; Methylsulfinylmethane; Methyl sulfoxide; Dimethyl sulphoxide; Dimethylsulfoxide; sulfinylbismethane; Demasorb; Domoso; Methane, sulfinylbis-

Section 2 — Hazards Identification

2.1 Classification of the substance or mixture

Classification basis: OSHA 29 CFR 1910.1200 Appendix A, aligned to the GHS Rev. 7 hazard classes.

Classification: Not classified. This substance meets no hazard class criteria of OSHA 29 CFR 1910.1200 Appendix A on the data reviewed.

2.2 Label elements

Signal word: None required

GHS pictograms: None

Section 9 — Physical and Chemical Properties

9.1 Information on basic physical and chemical properties

Physical form: Liquid

Appearance: Colorless liquid

Odor: Slightly sulfurous odor

Boiling point: 190°C (374°F) at 1013 hPa

Melting point: 18.4°C (65°F)

Flash point: 87°C (189°F) closed cup

Density: 1.100 at 20 °C/4 °C

Vapor pressure: 0.6 hPa at 20°C

Water solubility: Miscible

Log Pow (log Kow): -1.35

Vapor density: 2.71 (air = 1)

Auto-ignition temperature: 215°C (419°F)

Viscosity: 2.47 cP at 20°C

Not found in the public records searched: lower explosive limit, upper explosive limit and pH. Enter these from your supplier's safety data sheet or your own test report before the draft is issued.

Where each value came from

Odor — Hazardous Substances Data Bank (HSDB)
Lefaux, R. Practical Toxicology of Plastics. Cleveland: CRC Press Inc., 1968, p. 120
View the record
Melting point — Hazardous Substances Data Bank (HSDB)
O'Neil, M.J. (ed.). The Merck Index - An Encyclopedia of Chemicals, Drugs, and Biologicals. Cambridge, UK: Royal Society of Chemistry, 2013, p. 593
View the record
Density — Hazardous Substances Data Bank (HSDB)
Same reference as melting point above.
View the record
Water solubility — Hazardous Substances Data Bank (HSDB)
Dorigan J et al; Preliminary scoring of selected organic air pollutants. Appendix II-Chemistry, production, and toxicity of chemicals D through E. Research Triangle Park, NC: US EPA, USEPA-450/3-77-008C. pp.327 (1976)
View the record
Log Pow (log Kow) — Hazardous Substances Data Bank (HSDB)
Hansch, C., Leo, A., D. Hoekman. Exploring QSAR - Hydrophobic, Electronic, and Steric Constants. Washington, DC: American Chemical Society., 1995, p. 5
View the record
Vapor density — Hazardous Substances Data Bank (HSDB)
Verschueren, K. Handbook of Environmental Data on Organic Chemicals. Volumes 1-2. 4th ed. John Wiley & Sons. New York, NY. 2001, p. 541
View the record
Auto-ignition temperature — Hazardous Substances Data Bank (HSDB)
National Fire Protection Association; Fire Protection Guide to Hazardous Materials. 14th Edition, Quincy, MA 2010, p. 325-52
View the record
Viscosity — Hazardous Substances Data Bank (HSDB)
Same reference as melting point above.
View the record

A value with no row here was assembled from more than one record, so no single record is credited for it. The draft you buy carries this table as an appendix covering all 16 sections.

Sources

  • ECHA C&L Inventory — harmonised CLP entry
  • Hazardous Substances Data Bank (HSDB)
  • PubChem — GHS classification
  • PubChem — compound record
  • PubChem — names and identifiers
  • PubChem — regulatory information
  • PubChem — toxicity data
  • PubChem — transport information

Sections 1.3 and 1.4 are withheld here because the supplier and emergency contact blocks carry your own company details in the draft you buy. Every draft needs review by a competent person before it is issued.

Measured values for Dimethyl sulfoxide, and where each one comes from

20 measured values for 11 properties, read from 2 public databases. On 2 properties the records differ. Each reading is shown with its own record. Follow any record to read the value at its source.

Boiling point

2 records agree

Used with vapour pressure to judge how readily the substance reaches the air you breathe.

Melting point

2 records agree

Fixes the physical state at handling temperature, which the label and the transport class depend on.

Flash point

1 record

The lowest temperature at which the liquid gives off enough vapour to ignite. It decides the GHS flammable liquid category.

95 °C (203 °F) (Open cup)
Hazardous Substances Data Bank (HSDB)

Auto-ignition temperature

1 record

The temperature at which the substance ignites with no spark or flame. It sets safe surface and process temperatures.

Vapour pressure

3 records differ

The higher it is, the faster the substance evaporates into the workplace air at room temperature.

Vapour density

1 record

Above 1 the vapour sinks and collects in pits, sumps and low enclosed spaces.

Density

2 records differ

Needed to convert between mass and volume on the label, in transport papers and in a spill estimate.

Solubility

4 records, each a different case

Determines spill behaviour, the right extinguishing media and the correct first-aid rinse.

Soluble in ethanol, acetone, ether, carbon tetrachloride, ethyl acetate
Hazardous Substances Data Bank (HSDB)
Soluble in chloroform and benzene
Hazardous Substances Data Bank (HSDB)

Partition coefficient (log Kow)

1 record

Indicates whether the substance accumulates in fat or in water, which drives the environmental sections.

Viscosity

1 record

Governs how far a spill spreads and how fast it soaks into a surface or a sorbent.

Odour

2 records, each a different case

Odour is a warning property only. Many substances are hazardous well below the concentration you can smell.

Distinctive garlic or oyster-like odor
Hazardous Substances Data Bank (HSDB)

These are the public records read for Dimethyl sulfoxide, published here unchanged. Where two records disagree, the draft you buy states the value and names the record behind it, so a reviewer can see what was chosen. Every draft needs review by a competent person before it is issued.

Get the full draft SDS for Dimethyl sulfoxide

The draft covers all 16 sections under OSHA 29 CFR 1910.1200 and GHS Rev. 7, or the CLP EC 1272/2008 layout for the EU. Each draft arrives as an editable .docx and a PDF with an appendix naming the source of each value, in about 60 seconds. $5 per document, no account.

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