Safety data sheet for Acetone

CAS 67-64-1

This is the free preview of a draft SDS for Acetone — Sections 1, 2 and 9, generated from the sources named below. The full 16-section draft, with your own company in Section 1, is $5 per document.

Typically documented by: Cleaners, nail products, adhesive removers.

Draft safety data sheet — preview

Sections 1, 2, 9 of 16

CAS number
67-64-1
Molecular formula
C3H6O
Molecular weight
58.08 g/mol
Signal word
Danger

Hazard classification

  • GHS02 — Flammable
  • GHS07 — Health hazard — irritant
  • H225: Highly flammable liquid and vapor.
  • H319: Causes serious eye irritation.
  • H336: May cause drowsiness or dizziness.

Section 1 — Identification

1.1 Product identifier

Product identifier: Acetone

Chemical name (IUPAC): propan-2-one

CAS number: 67-64-1

PubChem CID reference: 180

Synonyms: acetone; 2-propanone; propanone; propan-2-one; Dimethyl ketone; Pyroacetic ether; Methyl ketone; Dimethylformaldehyde; beta-Ketopropane; Dimethylketal

Section 2 — Hazards Identification

2.1 Classification of the substance or mixture

Classification basis: OSHA 29 CFR 1910.1200 Appendix A, aligned to the GHS Rev. 7 hazard classes this sheet resolves: Flam. Liq. 2, Eye Irrit. 2, STOT SE 3.

Classification: Flammable Liquid, Category 2 (Flam. Liq. 2) [H225]

Classification: Eye Irritation, Category 2 (Eye Irrit. 2) [H319]

Classification: Specific Target Organ Toxicity, Single Exposure, Category 3 (STOT SE 3) [H336]

2.2 Label elements

Signal word: Danger

GHS pictograms: GHS02 (Flammable), GHS07 (Exclamation)

Hazard statement: H225: Highly flammable liquid and vapor.

Hazard statement: H319: Causes serious eye irritation.

Hazard statement: H336: May cause drowsiness or dizziness.

Precautionary statement: P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Precautionary statement: P280: Wear protective gloves, protective clothing, eye protection, face protection, and hearing protection.

Precautionary statement: P233: Keep container tightly closed.

Precautionary statement: P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.

Precautionary statement: P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do - continue rinsing.

Precautionary statement: P337+P313: IF eye irritation persists: Get medical advice/attention.

Section 9 — Physical and Chemical Properties

9.1 Information on basic physical and chemical properties

Physical form: Liquid

Appearance: Colorless liquid

Odor: Fruity odor

Boiling point: 57°C (135°F) at 1013 hPa

Melting point: -94.9°C (-139°F)

Flash point: -20°C (-4°F) closed cup

Density: 0.7845 g/cm³ at 20°C

Vapor pressure: 240 hPa at 20°C

Water solubility: Miscible

Log Pow (log Kow): -0.24

Vapor density: 2 (air = 1)

Lower explosive limit: 2.6%

Upper explosive limit: 12.8%

Auto-ignition temperature: 465°C (869°F)

Viscosity: 0.32 cP at 20°C

pH: Not available

Occupational exposure limits for Acetone

The airborne limits on public record in the United States. These are transcribed from the tables named in each row, not derived. The full draft puts them in Section 8 with the control and PPE guidance.

OSHA PEL — TWA (8 h)

1000 ppm (2400 mg/m³)

OSHA Annotated PEL Table Z-1

NIOSH REL — TWA (up to 10 h)

250 ppm (590 mg/m³)

OSHA Annotated PEL Table Z-1 (NIOSH REL column)

Where each value came from

Odor — Hazardous Substances Data Bank (HSDB)
Verschueren, K. Handbook of Environmental Data on Organic Chemicals. Volumes 1-2. 4th ed. John Wiley & Sons. New York, NY. 2001, p. 107
View the record
Melting point — Hazardous Substances Data Bank (HSDB)
Haynes, W.M. (ed.). CRC Handbook of Chemistry and Physics. 95th Edition. CRC Press LLC, Boca Raton, FL: 2014-2015, p. 3-4
View the record
Flash point — Hazardous Substances Data Bank (HSDB)
National Fire Protection Association; Fire Protection Guide to Hazardous Materials. 14th Edition, Quincy, MA 2010, p. 325-10
View the record
Density — Hazardous Substances Data Bank (HSDB)
Same reference as melting point above.
View the record
Water solubility — Hazardous Substances Data Bank (HSDB)
O'Neil, M.J. (ed.). The Merck Index - An Encyclopedia of Chemicals, Drugs, and Biologicals. Cambridge, UK: Royal Society of Chemistry, 2013, p. 13
View the record
Log Pow (log Kow) — Hazardous Substances Data Bank (HSDB)
Hansch, C., Leo, A., D. Hoekman. Exploring QSAR - Hydrophobic, Electronic, and Steric Constants. Washington, DC: American Chemical Society., 1995, p. 6
View the record
Vapor density — Hazardous Substances Data Bank (HSDB)
CDC; International Chemical Safety Cards (ICSC) 2012. Atlanta, GA: Centers for Disease Prevention & Control. National Institute for Occupational Safety & Health (NIOSH). Ed Info Div
View the record
Lower explosive limit — Hazardous Substances Data Bank (HSDB)
Lewis, R.J. Sr. (ed) Sax's Dangerous Properties of Industrial Materials. 11th Edition. Wiley-Interscience, Wiley & Sons, Inc. Hoboken, NJ. 2004, p. 22
View the record
Auto-ignition temperature — Hazardous Substances Data Bank (HSDB)
Same reference as flash point above.
View the record
Viscosity — Hazardous Substances Data Bank (HSDB)
Howard HL; Acetone. Kirk-Othmer Encyclopedia of Chemical Technology. (1999-2015). New York, NY: John Wiley & Sons. Online Posting Date: Jan 14, 2011
View the record

A value with no row here was assembled from more than one record, so no single record is credited for it. The draft you buy carries this table as an appendix covering all 16 sections.

Sources

  • ECHA C&L Inventory — harmonised CLP entry
  • Hazardous Substances Data Bank (HSDB)
  • OSHA Annotated PEL Table Z-1
  • OSHA Annotated PEL Table Z-1 (NIOSH REL column)
  • PubChem — GHS classification
  • PubChem — compound record
  • PubChem — names and identifiers
  • PubChem — regulatory information
  • PubChem — toxicity data
  • PubChem — transport information

Sections 1.3 and 1.4 are withheld here because the supplier and emergency contact blocks carry your own company details in the draft you buy. Every draft needs review by a competent person before it is issued.

Measured values for Acetone, and where each one comes from

32 measured values for 12 properties, read from 4 public databases. On 4 properties the records differ. Each reading is shown with its own record. Follow any record to read the value at its source.

Boiling point

4 records agree

Used with vapour pressure to judge how readily the substance reaches the air you breathe.

Melting point

4 records, -96 to -94 °C

Fixes the physical state at handling temperature, which the label and the transport class depend on.

Flash point

5 records, -20 to -17 °C

The lowest temperature at which the liquid gives off enough vapour to ignite. It decides the GHS flammable liquid category.

-16.99 °C (1.42 °F) - closed cup
Hazardous Substances Data Bank (HSDB)
-4 °F (-20 °C) (Closed cup)
Hazardous Substances Data Bank (HSDB)

Auto-ignition temperature

1 record

The temperature at which the substance ignites with no spark or flame. It sets safe surface and process temperatures.

Explosive limits

1 record

The vapour concentration range in air that will burn. Below the lower limit and above the upper limit it will not.

Vapour pressure

4 records differ

The higher it is, the faster the substance evaporates into the workplace air at room temperature.

Vapour density

1 record

Above 1 the vapour sinks and collects in pits, sumps and low enclosed spaces.

Density

4 records differ

Needed to convert between mass and volume on the label, in transport papers and in a spill estimate.

Solubility

4 records, each a different case

Determines spill behaviour, the right extinguishing media and the correct first-aid rinse.

Miscible with alcohol, dimethylformamide, ether
Hazardous Substances Data Bank (HSDB)

Partition coefficient (log Kow)

1 record

Indicates whether the substance accumulates in fat or in water, which drives the environmental sections.

Viscosity

1 record

Governs how far a spill spreads and how fast it soaks into a surface or a sorbent.

0.32 cP at 20 °C; 0.27 cP at 40 °C
Hazardous Substances Data Bank (HSDB)

Odour

2 records, each a different case

Odour is a warning property only. Many substances are hazardous well below the concentration you can smell.

These are the public records read for Acetone, published here unchanged. Where two records disagree, the draft you buy states the value and names the record behind it, so a reviewer can see what was chosen. Every draft needs review by a competent person before it is issued.

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